Lecture Notes: The Teflon Story and the PFAS Problem
Introduction
In 1929, mysterious deaths in Chicago were linked to refrigerators leaking toxic gases.
DuPont, a chemical company, sought safer alternatives for these refrigerator gases, leading to the discovery of Teflon.
Discovery of Teflon
Roy J. Plunkett at DuPont discovered polytetrafluoroethylene (PTFE), later known as Teflon, while experimenting with tetrafluoroethylene (TFE).
Teflon was found to be remarkably inert due to strong carbon-fluorine bonds.
Initially used in military applications during World War II, particularly for nuclear bomb fuel processing.
Commercialization of Teflon
DuPont trademarked Teflon in 1944 and began commercial production after the war, leading to widespread use in non-stick cookware and other applications.
Environmental and Health Impacts
C8, a processing aid for Teflon, was discovered to be toxic and persistent in the environment.
Studies in the 1960s showed that C8 could cause liver enlargement and was linked to various health issues.
Massive contamination was found, affecting animals and humans globally.
Legal and Regulatory Issues
DuPont faced lawsuits for poisoning water supplies with C8, notably in Parkersburg, West Virginia.
A 2013 study confirmed links between C8 and several diseases, including certain cancers.
DuPont phased out C8 but replaced it with GenX, which also posed health risks.
The PFAS Family
PFAS (per- and polyfluoroalkyl substances) include over 14,000 chemicals, known for their persistence in the environment.
They are used in a variety of consumer products, creating widespread contamination.
PFAS are often referred to as "forever chemicals" due to their inability to break down.
Health Implications and Public Awareness
PFAS are found in the blood of nearly all Americans and are linked to various health issues.
Public awareness is critical, with efforts to reduce exposure and demand safer alternatives.
Efforts to Address PFAS Contamination
New regulations aim to limit PFAS in drinking water to extremely low levels.
Researchers and companies are developing filtration methods and safer alternatives.
Conclusion
The story of Teflon and PFAS highlights the challenges of balancing technological advancements with environmental and health safety.
Ongoing research and public activism are crucial in addressing the legacy of PFAS and preventing similar issues in the future.