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Understanding Metallic Properties and Bonding

May 5, 2025

Lecture on Metallic Properties and Bonding

Overview

  • Metals differ significantly from most other elements.
  • Key properties of metals:
    • High melting points (mostly, except Group 1 metals)
    • Excellent conductors of electricity and heat
    • High density
    • High tensile strength
    • Ductile (can be made into wires)
    • Malleable (can be shaped into sheets)

Explanation of Metallic Properties

  • Metallic Bonding:
    • Metals are formed by atoms losing their last valence electrons.
    • Atoms become cations (positively charged).
    • Electrons become delocalized, forming a "sea of delocalized electrons."
    • Attraction between these free electrons and cations is known as metallic bonding.

Key Properties Explained Through Metallic Bonding

High Melting Points

  • Strong forces of attraction (metallic bonds) require a large amount of energy to break.

Conductivity

  • Sea of delocalized electrons allows effective conduction of electrical and thermal energy.

High Density and Strength

  • Strong attraction among cations and electrons contributes to high density and tensile strength.

Ductility and Malleability

  • Layers of cations can slide over each other:
    • Ductility: ability to form wires.
    • Malleability: ability to be hammered into sheets.

Summary

  • The unique properties of metals are largely due to the nature of metallic bonding.
  • Understanding the behavior of these delocalized electrons and cations explains why metals are strong, conductive, and malleable.