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7.12 - Naturally Occurring Polymers

Sep 2, 2025

Overview

This lecture covers naturally occurring polymers, focusing on polypeptides, DNA, and carbohydrates, explaining their monomer units and how they form larger structures.

Polypeptides and Proteins

  • Polypeptides are polymers made from linking many amino acids in a chain.
  • Proteins are made when polypeptides fold or combine; different sequences lead to many types of proteins.
  • Proteins serve various functions, such as catalyzing reactions (enzymes) and providing structure in tissues.
  • Amino acids have two key functional groups: a carboxyl (carboxylic acid) group and an amino group, joined by a central carbon.
  • The "R group" differs between amino acids, giving each its unique properties.
  • Amino acids link via condensation reactions, forming bonds between the carbon of one and the nitrogen of another, releasing water.
  • The linkage formed is called a peptide bond, amide bond, or amide link.
  • The polymerization process can be represented by a general equation showing amino acids joining and producing water.

DNA

  • DNA is a polymer whose monomers are nucleotides.
  • Each nucleotide contains a base (T, A, G, or C) and a sugar-phosphate backbone.
  • There are four types of nucleotides, one for each base.
  • The sequence of nucleotides encodes genetic information as genes.
  • DNA consists of two polymer chains connected together, forming a double helix.

Carbohydrates

  • Carbohydrates include a variety of polymers (polysaccharides) and monomers (sugars), made from carbon, hydrogen, and oxygen.
  • Polysaccharides include starch, cellulose, and glycogen.
  • Monosaccharides (sugars) include glucose and fructose.
  • Polymers form by joining many monosaccharides, like making starch from multiple glucose units.

Key Terms & Definitions

  • Polymer — a long chain molecule made from repeating smaller units called monomers.
  • Monomer — the basic repeating unit that joins to form a polymer.
  • Amino Acid — the monomer unit of polypeptides and proteins, containing amino and carboxyl groups.
  • Peptide Bond (also called amide bond or amide link) — the bond joining amino acids in a polypeptide.
  • Nucleotide — the monomer of DNA, containing a base, a sugar, and a phosphate group.
  • Polysaccharide — a carbohydrate polymer made from many monosaccharide units.
  • Monosaccharide — a single sugar unit, such as glucose or fructose.

Action Items / Next Steps

  • Review the structure of amino acids and practice drawing peptide bond formation.
  • Learn the basic structure of nucleotides and how DNA strands pair up.
  • Memorize examples of polysaccharides and monosaccharides.