4.5 - The Reactivity Series & Displacement Reactions

Sep 2, 2025

Overview

This lecture covers the reactivity series of metals, their reactions with acids and water, and how the series predicts outcomes of displacement reactions.

The Reactivity Series of Metals

  • The reactivity series ranks metals by how easily they form positive ions.
  • Group 1 metals are most reactive, group 2 metals are less reactive, and transition metals are generally least reactive.
  • Carbon and hydrogen, though not metals, are often included in the series as reference points.

Metals Reacting with Acids

  • Metals react with acids to produce a salt and hydrogen gas.
  • Highly reactive metals (like potassium) react violently or explosively with acids.
  • Less reactive metals (like magnesium, zinc, and iron) react with decreasing intensity.
  • Copper usually does not react with acids.
  • The amount of heat produced indicates the metal's reactivity.
  • To compare reactivity fairly, keep metal mass, surface area, and acid concentration the same.

Metals Reacting with Water

  • Reactive metals form metal hydroxides and hydrogen gas when reacting with water.
  • Only the most reactive metals (e.g., lithium) react readily with water.
  • Magnesium reacts only slightly with water.
  • Zinc, iron, and copper do not react with water.

Displacement Reactions

  • A more reactive metal can displace a less reactive metal from its compound in solution.
  • Magnesium can displace iron from iron sulfate, forming magnesium sulfate and iron.
  • Copper cannot displace iron from iron sulfate as it is less reactive.

Key Terms & Definitions

  • Reactivity Series — An ordered list of metals based on how readily they form positive ions.
  • Displacement Reaction — A reaction where a more reactive element replaces a less reactive one in a compound.

Action Items / Next Steps

  • Review the order of metals in the reactivity series.
  • Practice predicting the products of metal reactions with acids, water, and in displacement reactions.