Ionic Bonds and Electron Transfer

Jun 9, 2025

Overview

This lecture explains ionic bonds, focusing on how they form between metals and non-metals due to large differences in electronegativity, using sodium and chlorine as examples.

Types of Chemical Bonds

  • Three main bond types: covalent (non-polar and polar), ionic, and hydrogen bonds.
  • Ionic bonds are attractions between ions of opposite charge.

Basics of Ionic Bonds

  • Ionic bonds form when electrons are transferred from one atom to another, resulting in charged ions.
  • Opposite charges (positive and negative) attract, creating the ionic bond.
  • Typically occur between metals (low electronegativity) and non-metals (high electronegativity) on the periodic table.

Role of Electronegativity

  • Electronegativity is an atom’s ability to pull electrons toward itself.
  • Increases left to right and bottom to top on the periodic table.
  • Large difference in electronegativity between two atoms promotes ionic bond formation.

Formation of Ions: Sodium & Chlorine Example

  • Sodium (Na), atomic number 11: 11 protons, 11 electrons, 1 electron in outer shell.
  • Chlorine (Cl), atomic number 17: 17 protons, 17 electrons, 7 electrons in outer shell.
  • Atoms seek full outer electron shells to be stable.
  • Sodium loses 1 electron to become Na⁺ (cation), now 10 electrons and 11 protons.
  • Chlorine gains 1 electron to become Cl⁻ (anion), now 18 electrons and 17 protons.

Formation of Sodium Chloride (NaCl)

  • Na⁺ and Cl⁻ are attracted due to opposite charges and form the compound sodium chloride (table salt).
  • In solid form, sodium chloride is a crystal; in water, it dissociates into ions.

Importance of Ions and Ionic Bonds

  • Ions are involved in many physiological processes, especially in water and across cell membranes.
  • Ionic bonds involve the transfer of electrons; atoms become ions with unequal numbers of protons and electrons.
  • Positive ions are called cations; negative ions are called anions.

Key Terms & Definitions

  • Ion — An atom with a net electrical charge due to loss or gain of electrons.
  • Electronegativity — The strength an atom has to attract electrons in a bond.
  • Cation — Positively charged ion (e.g., Na⁺).
  • Anion — Negatively charged ion (e.g., Cl⁻).
  • Ionic Bond — Attraction between cations and anions.

Action Items / Next Steps

  • Review section on electron configurations and practice drawing them.
  • Prepare for discussion on hydrogen bonds in the next class.