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Collision Theory Overview

Jul 22, 2025

Overview

This lecture explains collision theory, including its definition, significance of orientation and temperature, and why reactions often occur in steps.

Collision Theory Basics

  • Collision theory states that atoms or molecules must collide to react.
  • Successful reactions require collisions with sufficient energy and correct orientation.

Importance of Orientation

  • Correct orientation means atoms must be aligned properly during collision for a reaction to occur.
  • Example: Only specific atoms on different molecules must collide for a reaction; wrong alignments don't react.

Role of Temperature and Concentration

  • Increasing temperature causes molecules to move faster, raising collision chance and energy.
  • Higher concentration means more molecules in solution, increasing collision likelihood.
  • Both higher temperature and concentration speed up reaction rates.

Reaction Steps

  • Simultaneous collision of many molecules is rare due to low probability of correct orientation and energy.
  • Reactions often proceed in steps, allowing fewer molecules to interact at each stage.
  • Reaction steps form intermediates that can react further, making the process more feasible.

Key Terms & Definitions

  • Collision Theory — The idea that atoms/molecules must collide with enough energy and the correct orientation to react.
  • Orientation — The specific alignment required between reacting atoms for a reaction to occur.
  • Concentration — The amount of reactant molecules in a solution.
  • Reaction Steps — Stages in a reaction where smaller groups of molecules combine, often forming intermediates.

Action Items / Next Steps

  • Review textbook sections on collision theory and reaction mechanisms.
  • Practice identifying reaction steps and intermediates for sample reactions.