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Understanding Acid-Base Titration Techniques

Apr 24, 2025

Lecture on Acid-Base Titration

Introduction to Titration

  • Acid-Base Titration: A method to determine the concentration of an acid or base in a solution.
  • Process: Involves measuring the volume of a titrant (acid or base) needed to completely react with the solution.
  • Comparison to Stoichiometry: Similar concept, involving precise measurements and calculations.

Titration Curve

  • Plot: pH is plotted against the volume of titrant added.
  • Behavior of pH:
    • Initially rises slowly as base is added.
    • Sharp rise near the equivalence point.
  • Equivalence Point: The point where the amount of titrant added exactly neutralizes the acid in the solution.

Indicators

  • Function: Substances used to signal the equivalence point by changing color.
  • Example: Sharp color change indicates that the equivalence point has been reached.

Equivalence Point Details

  • Strong Acid with Strong Base: Equivalence point at pH 7.
  • Weak Acids/Bases: Equivalence point will differ from 7.

Example Problem

  • Given: A sodium hydroxide solution of unknown concentration.
  • Reactants: 3.0M sulfuric acid used to titrate 25 mL of sodium hydroxide.
  • Result: 11.6 mL of acid required to reach equivalence point.
  • Calculation:
    • Convert volumes to liters.
    • Use conversion factors and stoichiometric ratios to determine reactant concentrations.

Conclusion

  • Purpose: Understanding the process and calculation in titration helps determine unknown concentrations.
  • Next Steps: Practice with various examples to solidify understanding.

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