Lecture on Acid-Base Titration
Introduction to Titration
- Acid-Base Titration: A method to determine the concentration of an acid or base in a solution.
- Process: Involves measuring the volume of a titrant (acid or base) needed to completely react with the solution.
- Comparison to Stoichiometry: Similar concept, involving precise measurements and calculations.
Titration Curve
- Plot: pH is plotted against the volume of titrant added.
- Behavior of pH:
- Initially rises slowly as base is added.
- Sharp rise near the equivalence point.
- Equivalence Point: The point where the amount of titrant added exactly neutralizes the acid in the solution.
Indicators
- Function: Substances used to signal the equivalence point by changing color.
- Example: Sharp color change indicates that the equivalence point has been reached.
Equivalence Point Details
- Strong Acid with Strong Base: Equivalence point at pH 7.
- Weak Acids/Bases: Equivalence point will differ from 7.
Example Problem
- Given: A sodium hydroxide solution of unknown concentration.
- Reactants: 3.0M sulfuric acid used to titrate 25 mL of sodium hydroxide.
- Result: 11.6 mL of acid required to reach equivalence point.
- Calculation:
- Convert volumes to liters.
- Use conversion factors and stoichiometric ratios to determine reactant concentrations.
Conclusion
- Purpose: Understanding the process and calculation in titration helps determine unknown concentrations.
- Next Steps: Practice with various examples to solidify understanding.
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