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Chemical Reaction Types Overview

Sep 4, 2025

Overview

This lecture covers the main types of chemical reactions: synthesis, decomposition, combustion, single replacement, and double replacement reactions, including their general forms and key examples.

Synthesis (Combination) Reactions

  • Multiple reactants combine to form a single product (A + B → AB).
  • Example: Zinc + Oxygen → Zinc oxide.
  • Example: Barium oxide + Carbon dioxide → Barium carbonate.

Decomposition Reactions

  • A single compound breaks down into two or more products (AB → A + B).
  • Example: Magnesium nitride decomposes on heating to Magnesium + Nitrogen gas.
  • Example: Heating Calcium carbonate → Calcium oxide + Carbon dioxide.

Combustion Reactions

  • Involves reaction of a hydrocarbon (CxHy or CxHyOz) with oxygen to yield carbon dioxide and water.
  • Example: Propane + Oxygen → Carbon dioxide + Water.
  • Example: Ethanol + Oxygen → Carbon dioxide + Water (with enough oxygen present).
  • Combustion reactions are highly exothermic (release heat energy).

Single Replacement Reactions

  • An element replaces another in a compound (A + BC → AC + B).
  • Metal replaces metal: Zinc + Copper(II) chloride → Zinc chloride + Copper.
  • Non-metal replaces non-metal: Bromine + Sodium iodide → Sodium bromide + Iodine.

Double Replacement Reactions

  • Two compounds exchange partners (AB + CD → AD + CB).
  • Example: Calcium chloride + Sodium nitrate → Calcium nitrate + Sodium chloride.
  • Cations pair with a different anion, and vice versa.
  • Ions with opposite charges attract; like charges do not pair.

Special Double Replacement Reactions

  • Precipitation Reaction: Mixing solutions forms an insoluble solid (precipitate), e.g., Calcium nitrate + Sodium phosphate → Sodium nitrate + Calcium phosphate (solid).
  • Gas Evolution Reaction: Produces a gas, e.g., Sodium sulfide + Hydrochloric acid → Sodium chloride + Hydrogen sulfide (gas).
  • Acid-Base Neutralization: Acid and base form water and a salt, e.g., Hydrochloric acid + Sodium hydroxide → Sodium chloride + Water.

Key Terms & Definitions

  • Synthesis Reaction — Multiple reactants form one product.
  • Decomposition Reaction — One reactant breaks into multiple products.
  • Combustion Reaction — Hydrocarbon reacts with oxygen to produce CO₂ and H₂O.
  • Single Replacement Reaction — An element replaces another in a compound.
  • Double Replacement Reaction — Two compounds exchange ions to form new compounds.
  • Precipitation Reaction — A double replacement reaction forming a solid product.
  • Gas Evolution Reaction — A reaction that produces a gas product.
  • Acid-Base Neutralization — Acid and base react to form water and a salt.

Action Items / Next Steps

  • Review examples of each reaction type.
  • Practice writing and balancing equations for all five reaction types.