Electron Configurations Overview

Jun 12, 2025

Overview

This lecture explains how to write electron configurations for elements, including both full and condensed forms, with step-by-step examples from each block of the periodic table.

Electron Configuration Basics

  • Electron configuration shows how electrons are arranged in atomic orbitals for an element.
  • There are four subshells: s, p, d, and f.
  • s subshell: 1 orbital, holds up to 2 electrons.
  • p subshell: 3 orbitals, holds up to 6 electrons.
  • d subshell: 5 orbitals, holds up to 10 electrons.
  • f subshell: 7 orbitals, holds up to 14 electrons.

Periodic Table Blocks

  • s block: first two groups and helium.
  • p block: right side of the table.
  • d block: inner transition metals.
  • f block: elements in the two bottom rows.

Writing Electron Configurations

  • Always start from hydrogen and move left to right across the periodic table to the desired element.
  • The order of filling orbitals (Aufbau principle) is crucial.
  • s block example (Beryllium): 1s² 2s².
  • p block example (Sulfur): 1s² 2s² 2p⁶ 3s² 3p⁴.
  • d block example (Iron): 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d⁶ (note: d block’s number is one less than the period).
  • f block example (Plutonium): 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p⁶ 5s² 4d¹⁰ 5p⁶ 6s² 4f¹⁴ 5d¹⁰ 6p⁶ 7s² 5f⁶ (note: f block’s number is two less than period).

Condensed (Shorthand) Electron Configurations

  • Use the noble gas from the previous row as a placeholder in brackets.
  • For sulfur: [Ne] 3s² 3p⁴.
  • For iron: [Ar] 4s² 3d⁶.
  • For plutonium: [Rn] 7s² 5f⁶.

Key Terms & Definitions

  • Electron Configuration — The arrangement of electrons in an atom’s orbitals.
  • Subshell (s, p, d, f) — Types of orbitals with specific shapes and electron capacities.
  • Block — Sections of the periodic table based on subshell filling.
  • Condensed/Shorthand Configuration — A shorter way to write electron configurations using noble gas notation.

Action Items / Next Steps

  • Practice writing full and condensed electron configurations for various elements.
  • Review the periodic table’s blocks and subshell order.
  • Watch the suggested practice quiz video for step-by-step answers.