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Atomic Structure Overview

Jul 21, 2025

Overview

This lecture reviews basic atomic structure, focusing on the components of the atom, their properties, forces within atoms, and concepts concerning ions.

Structure of the Atom

  • Atoms have a central nucleus containing protons and neutrons.
  • Electrons are found outside the nucleus, forming the electron cloud.
  • The atom is mostly empty space; the nucleus is much smaller than the electron cloud.
  • 99% of an atom's mass is concentrated in the nucleus.

Subatomic Particles and Charges

  • Protons have a positive charge and are found in the nucleus.
  • Neutrons are electrically neutral and also in the nucleus.
  • Electrons have a negative charge and orbit the nucleus.
  • Opposite charges attract, so electrons are attracted to the nucleus.

Why Electrons Stay in Orbit

  • Electrons are kept in orbit by a balance of their speed (tangential velocity) and electrostatic attraction to protons.
  • Electrons can escape the atom if they gain enough energy, becoming ions.
  • Electron capture is when an electron falls into the nucleus, changing the element.

Forces Within the Nucleus

  • Protons repel each other due to like charges, but the strong nuclear force keeps the nucleus together.
  • The strong nuclear force is much stronger than the electrostatic force.

Mass of Subatomic Particles

  • Neutrons are slightly heavier than protons.
  • Both protons and neutrons have a mass of approximately 1 atomic mass unit (amu).
  • The electron’s mass is negligible (~0.000549 amu).

Atoms vs. Ions and Net Charge

  • Atoms are electrically neutral with equal numbers of protons and electrons.
  • An ion has unequal numbers of protons and electrons, resulting in a net charge.
  • The net charge equals the number of protons minus the number of electrons.
  • A cation is a positively charged ion; an anion is a negatively charged ion.
  • Ions do not necessarily have equal numbers of protons and neutrons.

Key Terms & Definitions

  • Electron — negatively charged particle orbiting the nucleus.
  • Proton — positively charged particle in the nucleus.
  • Neutron — electrically neutral particle in the nucleus.
  • Nucleus — central core of the atom containing protons and neutrons.
  • Ion — atom with unequal numbers of protons and electrons, carrying a net charge.
  • Cation — positively charged ion.
  • Anion — negatively charged ion.
  • Strong nuclear force — force holding protons and neutrons together in the nucleus.

Action Items / Next Steps

  • Review key definitions and mass/charge properties of atomic particles.
  • Practice calculations of net charge for atoms and ions.
  • Look up electron capture for further understanding.