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Polyatomic Ions Overview

Sep 22, 2025

Overview

This lecture covers the names, formulas, and charges of common polyatomic ions essential for honors-level chemistry.

Common Polyatomic Ions and Their Formulas

  • Acetate: C₂H₃O₂⁻ or CH₃COO⁻
  • Ammonium: NH₄⁺
  • Carbonate: CO₃²⁻
  • Bicarbonate (Hydrogen carbonate): HCO₃⁻
  • Chlorate: ClO₃⁻
  • Chlorite: ClO₂⁻
  • Chromate: CrO₄²⁻
  • Dichromate: Cr₂O₇²⁻
  • Cyanide: CN⁻
  • Hydroxide: OH⁻
  • Nitrate: NO₃⁻
  • Nitrite: NO₂⁻
  • Permanganate: MnO₄⁻
  • Phosphate: PO₄³⁻
  • Hydrogen phosphate: HPO₄²⁻
  • Dihydrogen phosphate: H₂PO₄⁻
  • Sulfate: SO₄²⁻
  • Sulfite: SO₃²⁻
  • Hydrogen sulfate (bisulfate): HSO₄⁻
  • Hydrogen sulfite (bisulfite): HSO₃⁻

Charges of Key Polyatomic Ions

  • Most ions listed carry charges of -1, -2, or -3.
  • Ammonium is a unique positive polyatomic ion (NH₄⁺).
  • Phosphate family has -1 to -3 charges depending on hydrogen content.

Key Terms & Definitions

  • Polyatomic Ion — A charged particle composed of two or more atoms covalently bonded.
  • Acetate — C₂H₃O₂⁻; a common anion found in vinegar.
  • Ammonium — NH₄⁺; the only common polyatomic cation.
  • Carbonate — CO₃²⁻; an important ion in geology and biology.
  • Chlorate — ClO₃⁻; an oxidizing agent.
  • Dichromate — Cr₂O₇²⁻; used in cleaning and as an oxidizing agent.

Action Items / Next Steps

  • Memorize each polyatomic ion's name, formula, and charge.
  • Practice writing and recognizing these ions in chemical formulas.
  • Prepare for quizzes or exams covering polyatomic ions.