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Understanding Quaternary Protein Structures

Quaternary structure of proteins

This structure contains more than one polypeptide and simply means how different polypeptides are arranged together. In general, the same types of interactions that contribute to tertiary structure (mostly weak interactions, such as hydrogen bonding and London dispersion forces) also hold the subunits together to give quaternary

structure.

Quaternary structures of proteins can be conjugated or non-conjugated

Non-conjugated

Conjugated

Quaternary structure of proteins Conjugated

Conjugated proteins have one or more non-polypeptide subunits in proteins

addition to their polypeptides. Hemoglobin is an oxygen carrying protein consisting of 4 polypeptides. Each subunit contains one iron atom (prosthetic group) and can carry one molecule of oxygen.

https://en.wikipedia.org/wiki/Hemoglobin

Haemoglobin

Quaternary structure of proteins

Non-conjugated

Non conjugated proteins are composed only of polypeptides. The

together using the same interactions as in the tertiary structure.

structure is formed by linking several polypeptide chains

Insulin Collagen

Form and function in globular & fibrous proteins

The function of a protein depends on its form. This is also shown when considering fibrous and globular proteinns. Look at the examples below and discuss how any why these molecules are adapted to the function they carry out.

Form and function in globular & fibrous proteins

Compare the two types of tertiary structures for proteins in the table below to understand how the form relates to the function of proteins:

Form and function in globular & fibrous proteins

Compare the two types of tertiary structures for proteins in the table below to understand how the form relates to the function of proteins:

Fibrous proteins

Globular proteins

Shape

Long and narrow

Often only alpha helices in the secondary structure

Rounded/spherical

Alpha helices and beta-pleated sheets in secondary structure

Role

Structural (strength and support)

Functional (catalytic, transport etc)

Solubility

(Generally) insoluble in water

(Generally) soluble in water

Stability

Repetitive amino acid sequence

Irregular amino acid sequence

Sequence

Less sensitive to changes in pH and temp

More sensitive to changes in pH and temp

Examples

Collagen, myosin, fibrin, actin, keratin, elastin

Catalase, hemoglobin, insulin, immunoglobulins