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Understanding Covalent Bonds and Structures

May 13, 2025

Covalent Bonds and Their Representations

Introduction

  • Covalent Bonds
    • Formed by sharing electrons between atoms.
    • Different from ionic bonds where electrons are transferred.

Ionic Bonds Recap

  • Ionic bonds form when electrons are transferred, leading to oppositely charged ions attracting each other.
    • Example: Sodium and Chlorine.

Covalent Bond Formation

  • Occurs in non-metal elements (e.g., two chlorine atoms).
    • Atoms share electrons to achieve full outer shells.
    • Example: Each chlorine atom shares one electron.

Representation of Covalent Bonds

Dot and Cross Diagrams

  • Used to visualize which electrons belong to which atom.
  • Only outermost shells are drawn unless specified otherwise.
  • Atoms represented by dots and crosses to distinguish shared electrons.

Displayed Formula

  • Chemical symbols of atoms joined by lines.
  • Easier for larger molecules like glucose.
  • Limitation: Does not show 3D shape of molecules.

3D Models

  • Show actual arrangement of atoms.
  • More complex to predict shapes.

Example: Ammonia (NH3)

  • Molecular formula indicates one nitrogen and three hydrogen atoms.
  • Steps for Covalent Bonding:
    1. Draw out atoms (outermost shells).
    2. Each hydrogen needs one extra electron; nitrogen needs three.
    3. Hydrogen shares electrons with nitrogen for full outer shells.
    4. Draw as a dot and cross diagram or displayed formula.

Types of Substances Formed by Covalent Bonds

Simple Molecular Substances

  • Atoms joined by strong covalent bonds.
  • Weak intermolecular forces between molecules.
  • Examples: Chlorine, Ammonia, Water (H2O), Methane (CH4).

Polymers and Giant Covalent Structures

  • Polymers: Long chains of repeating units (monomers).
    • Used in plastics and textiles.
  • Giant Covalent Structures: Include silicon dioxide, diamond, graphite.
    • Strong due to extensive covalent bonding in a lattice.

Conclusion

  • Covalent bonds result in various molecular substances ranging from simple molecules to complex structures.
  • Understanding of drawing methods is crucial for visualizing molecular structures.