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1.2 - Elements, Isotopes & Relative Atomic Mass

Sep 1, 2025

Overview

This lecture explains atomic structure, nuclear symbols, the concept of isotopes, and how to calculate the relative atomic mass using isotope abundances.

Atomic Structure and Elements

  • An atom consists of a central nucleus (protons and neutrons) and electrons orbiting the nucleus.
  • The number of protons in the nucleus determines which element it is.
  • Hydrogen has one proton, helium has two protons and two neutrons.
  • The periodic table organizes all ~100 elements, each with its own box and nuclear symbol.
  • The atomic number (bottom left of each box) shows the number of protons and is unique to each element.
  • Atoms with the same number of protons are the same element.

Nuclear Symbols and the Periodic Table

  • Nuclear symbols use one or two letters to represent the element (e.g., C for carbon, Li for lithium).
  • Some symbols are based on Latin names, e.g., Na for sodium and Fe for iron.
  • The periodic table includes both the symbol and the element name for reference.

Isotopes

  • Isotopes are different forms of the same element with the same number of protons but different numbers of neutrons.
  • Example: Carbon-12 has six protons, six neutrons; Carbon-13 has six protons, seven neutrons.
  • Isotopes react chemically in the same way but have different masses.

Relative Atomic Mass

  • The relative atomic mass is the average mass of all isotopes of an element, weighted by their abundances.
  • Abundance refers to the percentage of each isotope found in nature.
  • To calculate:
    1. Multiply each isotope's mass by its abundance.
    2. Add the results.
    3. Divide by the total abundance.
  • Example for copper:
    • Copper-63: 69.2% abundance, mass 63.
    • Copper-65: 30.8% abundance, mass 65.
    • Calculation: (69.2 × 63 + 30.8 × 65) ÷ 100 = 63.6 (to one decimal place).
  • The symbol for relative atomic mass is Ar.

Key Terms & Definitions

  • Atom — the basic unit of matter with a nucleus (protons, neutrons) and electrons.
  • Atomic Number — the number of protons in an atom, unique for each element.
  • Isotope — atoms of the same element with different numbers of neutrons.
  • Abundance — the percentage of a particular isotope present in nature.
  • Relative Atomic Mass (Ar) — the weighted average mass of an element’s isotopes.

Action Items / Next Steps

  • Practice calculating relative atomic mass using provided isotope data.
  • Review the periodic table to memorize common element symbols and atomic numbers.