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Thyroid Hormone Synthesis Process

Jun 11, 2025

Overview

This lecture explains the step-by-step synthesis of thyroid hormones (T3 and T4) in the thyroid gland, emphasizing the HPT axis, molecular mechanisms, and critical enzymes involved.

Structure and Function of the Thyroid Gland

  • The thyroid gland is a butterfly-shaped organ located below the larynx in the anterior neck.
  • Thyroid follicles are the basic structural and functional units of the gland.
  • Follicular cells (simple cuboidal epithelium) surround the follicle and produce thyroid hormone.

Hypothalamic-Pituitary-Thyroid (HPT) Axis

  • The hypothalamus releases thyrotropin-releasing hormone (TRH) from the paraventricular nucleus.
  • TRH stimulates thyrotropes in the anterior pituitary to secrete thyroid-stimulating hormone (TSH).
  • TSH binds to receptors on thyroid follicular cells, activating intracellular signaling.

Intracellular Signaling and Thyroglobulin Synthesis

  • TSH binding activates a Gs protein, which activates adenylate cyclase to convert ATP to cAMP.
  • cAMP activates protein kinase A, which phosphorylates transcription factors.
  • Phosphorylated transcription factors stimulate transcription and translation of thyroglobulin (Tg).
  • Tg is packaged in the Golgi, exocytosed into the follicular lumen, forming the colloid.

Iodide Uptake and Oxidation

  • Iodide is transported into follicular cells via secondary active transport with sodium (NIS symporter).
  • Iodide is transported out of the cell into the lumen by the pendrin protein.
  • Thyroid peroxidase (TPO) oxidizes iodide (I-) to iodine (I0) in the lumen.

Hormone Assembly: Iodination and Coupling

  • Iodine attaches to tyrosine residues on thyroglobulin, forming MIT (monoiodotyrosine) and DIT (diiodotyrosine) through iodination.
  • Coupling reactions: DIT + DIT forms T4 (thyroxine), and MIT + DIT forms T3 (triiodothyronine).

Release of T3 and T4

  • Thyroglobulin with T3 and T4 is endocytosed back into the follicular cell.
  • Lysosomal enzymes cleave T3 and T4 from thyroglobulin.
  • Free T3 and T4 are exocytosed into the bloodstream.

Transport in Blood

  • T3 and T4 are transported in blood bound to thyroxine-binding globulin (TBG) due to their low water solubility.

Key Terms & Definitions

  • Thyrotropin-Releasing Hormone (TRH) — hormone from hypothalamus stimulating TSH release.
  • Thyroid-Stimulating Hormone (TSH) — hormone from pituitary stimulating thyroid hormone synthesis.
  • Thyroglobulin (Tg) — protein precursor for thyroid hormone synthesis.
  • Iodination — addition of iodine to tyrosine residues.
  • Thyroid Peroxidase (TPO) — enzyme catalyzing iodide oxidation and iodination.
  • MIT/DIT — monoiodotyrosine/diiodotyrosine, intermediates in hormone synthesis.
  • Thyroxine (T4) — primary thyroid hormone produced, contains four iodines.
  • Triiodothyronine (T3) — more active thyroid hormone, contains three iodines.
  • Thyroxine-Binding Globulin (TBG) — plasma protein transporting T3 and T4.

Action Items / Next Steps

  • Review the steps of thyroid hormone synthesis in order.
  • Prepare for the next lecture on the effects of thyroid hormone on target organs.