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Acid Naming Rules and Patterns

Sep 27, 2025

Overview

This lecture explains how to name acids in chemistry, distinguishing between acids with and without oxygen, and provides naming patterns and key examples.

Types of Acids

  • Acids always begin with hydrogen (H) in their formula.
  • There are two types: acids without oxygen and acids with oxygen.

Naming Acids Without Oxygen

  • Use the prefix "hydro-" to indicate no oxygen present.
  • Naming pattern: "hydro" + root of element + "ic acid."
  • Example: HCl is hydrochloric acid; HI is hydroiodic acid; HF is hydrofluoric acid.
  • "Hydro" signals no oxygen; "ic acid" is the naming ending.

Naming Acids With Oxygen

  • No prefix is used if oxygen is present.
  • The root comes from the polyatomic ion.
  • If the ion ends with "-ite," change to "-ous acid" (e.g., NO₂⁻ is nitrite → HNO₂ is nitrous acid).
  • If the ion ends with "-ate," change to "-ic acid" (e.g., NO₃⁻ is nitrate → HNO₃ is nitric acid).
  • For phosphite (PO₃³⁻), the acid is called phosphorous acid (H₃PO₃); phosphate (PO₄³⁻) becomes phosphoric acid (H₃PO₄).
  • Some acid names (e.g., phosphorous, phosphoric) include an extra "r" by convention.

Naming Mnemonics and Tips

  • "I ATE organIC apples despITE being poisonOUS" — "ate" ions become "ic" acids, "ite" ions become "ous" acids.
  • Always balance charges when writing acid formulas.

Key Terms & Definitions

  • Acid — A compound starting with H, producing H⁺ ions in solution.
  • Hydro- prefix — Indicates an acid without oxygen.
  • Polyatomic ion — An ion made of multiple atoms (e.g., NO₃⁻, PO₄³⁻).
  • "-ic acid" — Ending for acids from "-ate" ions.
  • "-ous acid" — Ending for acids from "-ite" ions.

Action Items / Next Steps

  • Practice acid naming problems provided in the description box.
  • Review polyatomic ions and their charges.
  • Sign up for live tutoring for more detailed explanations.