🧭

Membrane Potentials and Nernst Guide

Nov 24, 2025

Overview

The transcript explains how ion concentration gradients and membrane permeability create membrane potentials, focusing on potassium and the Nernst equation to compute equilibrium potentials.

Potassium Gradient and Membrane Potential

  • Inside cell K+ ≈ 150 mM; outside ≈ 5 mM; strong outward concentration gradient.
  • K+ exits cell, leaving behind impermeant anions that create negative intracellular charge.
  • Negative charge attracts K+ back; balance point is the K+ equilibrium potential.
  • For K+, equilibrium potential is about −92 mV under the stated concentrations.

Thought Experiment: Injecting Positive Charge

  • Adding positive charge makes membrane potential less negative (e.g., −92 mV to −46 mV).
  • Electrical attraction back into cell weakens; more K+ leaves down its gradient.
  • Leaving K+ increases negative intracellular charge, driving Vm back toward −92 mV.
  • As long as K+ gradient (150 in/5 out) and K+-only permeability hold, Vm returns to −92 mV.

Conditions Required to Generate a Membrane Potential

  • Two requirements:
    • Concentration gradient: ion “desire” to move.
    • Permeability: ion “means” to move through the membrane.
  • Without either gradient or permeability, no membrane potential develops.
  • With both present for K+, Vm reaches the K+ equilibrium potential (≈ −92 mV).

Nernst Equation and Equilibrium Potentials

  • Membrane potential for a single ion (equilibrium potential) given by: Vm = 61.5 × log10([ion]out/[ion]in).
  • For divalent ions (e.g., Ca2+), constant halves: 30.75 × log10([ion]out/[ion]in).
  • Sign and magnitude depend on charge and concentration ratio inside vs. outside.

Equilibrium Potentials and Ion Movements

IonChargeDirection of Net Movement (given typical gradients)Equilibrium Potential (mV)Notes on Calculation
K+ (Potassium)+1Out of the cell−92Uses 61.5 × log10([K+]out/[K+]in)
Na+ (Sodium)+1Into the cell+67Uses 61.5 × log10([Na+]out/[Na+]in)
Cl− (Chloride)−1Into the cell−86Uses 61.5 × log10([Cl−]out/[Cl−]in)
Ca2+ (Calcium)+2Into the cell+123Uses 30.75 × log10([Ca2+]out/[Ca2+]in)

Key Terms & Definitions

  • Membrane potential (Vm): Electrical potential difference across the cell membrane.
  • Equilibrium potential (Nernst potential): Vm at which an ion’s electrical and chemical gradients balance.
  • Concentration gradient: Difference in ion concentration across the membrane driving diffusion.
  • Permeability: Membrane’s ability to allow an ion to pass through channels.

Action Items / Next Steps

  • Practice computing equilibrium potentials using Vm = 61.5 × log10([out]/[in]) for monovalent ions.
  • Adjust constant to 30.75 for divalent ions like Ca2+.
  • Analyze scenarios by checking both gradient (desire) and permeability (means) to predict Vm behavior.