Understanding Ionic and Molecular Compounds

Mar 21, 2025

Identifying Ionic vs. Molecular Compounds

Importance

  • Understanding the difference between ionic and molecular compounds is crucial for naming compounds, as they have different naming conventions.

Ionic Compounds

  • Composed of ions: positive cations and negative anions.
  • Typically feature metals as cations.
  • Metals are located on the left side of the periodic table's staircase.
    • Exception: Hydrogen, though on the left, is a non-metal.
  • Examples of Ionic Compounds:
    • Sodium and Chlorine (NaCl): Sodium is a metal, so it's ionic.
    • Iron and Bromine (FeBr): Iron is a metal, so it's ionic.
    • Silver and Sulfur (Ag₂S): Silver is a metal, so it's ionic.

Molecular (Covalent) Compounds

  • Made from non-metals only.
  • Non-metals are on the right side of the periodic table, plus hydrogen.
  • Examples of Molecular Compounds:
    • Water (H₂O): Hydrogen and oxygen are non-metals, so it's molecular.
    • Carbon Dioxide (CO₂): Both carbon and oxygen are non-metals.
    • Phosphorus Hexafluoride (PF₆): Phosphorus and fluorine are non-metals.

Practice Examples

  • Potassium and Chlorine (KCl):
    • Potassium is a metal and chlorine is a non-metal, so it's ionic.
  • Nitrogen Dioxide (NO₂):
    • Both nitrogen and oxygen are non-metals, so it's molecular.
  • Hydrogen and Sulfur (H₂S):
    • Hydrogen and sulfur are non-metals, so it's molecular.
  • Iron, Sulfur, and Oxygen (FeSO₄):
    • Iron is a metal, indicating it's ionic.
  • Carbon, Hydrogen, and Oxygen (CH₄O):
    • All are non-metals, so it's molecular.
  • Lead, Chlorine, and Oxygen (PbCl₂O):
    • Lead is a metal, so it's ionic.

Additional Notes

  • The staircase on the periodic table distinguishes metals from non-metals.
  • Metals are typically shiny, good conductors, and solids, unlike non-metals.