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Understanding the Combined Gas Law

Mar 5, 2025

Lecture Notes: Combined Gas Law

Overview

  • The video covers the combined gas law, including:
    • When to use it.
    • Ensuring units are consistent.
    • Correct mathematical approaches.

When to Use the Combined Gas Law

  • Initial and Final Conditions: Use when you have both initial and final conditions of a gas.
  • Problem Example:
    • Initial Volume: 2.3 L
    • Initial Pressure: 1.3 ATM
    • Asked to find final volume when pressure is increased to 4.7 ATM.
    • Constant Temperature: Ignore temperature in this scenario.

Application of Boyle's Law

  • Steps:
    • Substitute given values into the equation.
    • Isolate V2 by dividing both sides by 4.7 ATM.
    • Cancel out units of ATM, leaving liters.
    • Result: V2 = 0.64 L

Key Point

  • Constant Conditions: When a variable is held constant, it can be omitted from the combined gas law.

Example Problem with Temperature

  • Variables Given:
    • Volume
    • Temperature
    • Pressure remains constant (omit it).
  • Temperature Conversion:
    • Convert Celsius to Kelvin by adding 273.
    • Always work with Kelvin for gas laws.
  • Solving Process:
    • Set up equation.
    • Solve for V2 by multiplying and dividing correctly.
    • Result: V2 = 3.13 L

Another Example

  • Initial Conditions:
    • Units in Celsius and mmHg need conversion.
  • Conversion Steps:
    • Celsius to Kelvin: Add 273.15.
    • mmHg to Atmospheres: Divide by 760 (conversion factor: 1 ATM = 760 mmHg).
    • Ensure all units are consistent.
  • Calculations:
    • Solve for V2 using the consistent units.
    • Result: V2 = 8.6 L

Important Reminders

  • Consistency in Units: Ensure all variables are in the same units for successful calculations.
  • Kelvin: Always convert temperatures to Kelvin when dealing with gas laws.