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3.2 - Moles & Mass

Sep 2, 2025

Overview

This lecture explains the concept of the mole in chemistry, how to convert between moles, mass, and relative formula mass, and its application in chemical equations.

The Mole Concept

  • The mole is a unit used to measure the amount of a chemical substance.
  • One mole contains 6.02 × 10²³ particles (atoms, molecules, ions, or electrons), known as Avogadro's constant.
  • The number is chosen so that one mole of any substance has a mass in grams equal to its relative atomic or formula mass.

Mass, Moles, and Relative Formula Mass

  • The mass of one mole of carbon (relative atomic mass 12) is 12 grams.
  • The mass of one mole of oxygen (relative formula mass 32) is 32 grams.
  • The mass of one mole of CO₂ (relative formula mass 44) is 44 grams.
  • The relationship for calculating moles:
    Moles = mass (g) ÷ relative formula mass (Mr).
  • To find moles in 42.5 g of ammonia (NH₃, Mr = 17): 42.5 ÷ 17 = 2.5 moles.
  • Rearranged, mass = number of moles × Mr.
  • For 3 moles of CO₂ (Mr = 44): 3 × 44 = 132 g.

Calculating Element Mass in Compounds

  • To find the mass of a specific element in a compound:
    Multiply number of moles by the element's relative atomic mass.
  • For carbon in 3 moles of CO₂: 3 × 12 = 36 g.
  • Subtract the element mass from total compound mass to find the mass of the other element(s): 132 g (total) − 36 g (carbon) = 96 g (oxygen).

Chemical Equations and Mole Ratios

  • Chemical equations can be interpreted as ratios of moles reacting and produced.
  • Example: 1 mole magnesium reacts with 2 moles hydrochloric acid to produce 1 mole magnesium chloride and 1 mole hydrogen gas.
  • Ratios scale proportionally (e.g., 2 moles magnesium need 4 moles hydrochloric acid).

Key Terms & Definitions

  • Mole — unit representing 6.02 × 10²³ particles of a substance.
  • Avogadro's constant — the number 6.02 × 10²³, representing particles per mole.
  • Relative atomic mass (Ar) — average mass of an atom relative to carbon-12.
  • Relative formula mass (Mr) — sum of the relative atomic masses in a compound.
  • Mole ratio — proportion of moles of reactants and products in a chemical equation.

Action Items / Next Steps

  • Practice using the formula moles = mass ÷ Mr with different substances.
  • Review how to interpret and scale mole ratios in chemical equations.