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Understanding Acids, Bases, and Salts

May 12, 2025

Lecture Notes: Acids, Bases, and Salts

Definitions

  • Acid: Proton donor; donates H⁺ ions in a reaction.
  • Base: Proton acceptor; reacts to form OH⁻ ions when dissolved in water.
  • Alkali: A base that dissolves in water.
  • Salt: Ionic substance formed from the reaction of an acid with a base.

Key Concepts

  • Proton (H⁺): In the context of acids, refers to a hydrogen ion, which is a hydrogen atom that has lost its electron.
  • Concentration: A concentrated solution has a small amount of water; a dilute solution has a large amount of water.

Types of Acids and Bases

  • Strong Acid: Fully ionizes in solution (e.g., HCl, H₂SO₄).
  • Weak Acid: Partially ionizes in solution (e.g., CH₃COOH).
  • Strong Base: Fully ionizes in solution (e.g., NaOH, KOH).
  • Weak Base: Partially ionizes in solution (e.g., NH₃).

pH Scale

  • Ranges from 0 to 14.
  • Acids: pH < 7
    • Strong acid: pH 1-3
    • Weak acid: pH 4-6
  • Neutral: pH = 7 (e.g., water, NaCl solution)
  • Bases: pH > 7
    • Strong base: pH 11-14
    • Weak base: pH 8-10

Identifying Acids and Bases

  • Acids often start with an "H" (e.g., HCl).
  • Bases often end with "OH" or contain "O" (e.g., NaOH, CaO).

Reactions

  • Neutralization: Acid + Base → Salt + Water
  • Acid + Metal: Acid + Metal → Salt + Hydrogen gas
  • Acid + Carbonate: Acid + Carbonate → Salt + CO₂ + Water
  • Base + Ammonium Salt: Base + Ammonium Salt → Ammonia gas + Water

Indicators

  • Litmus:
    • Acid: Red
    • Base: Blue
  • Universal Indicator: Provides a range of colors to indicate pH level.
  • Phenolphthalein:
    • Base: Pink
    • Neutral/Acid: Colorless
  • Methyl Orange:
    • Acid: Red
    • Base: Yellow
    • Neutral: Orange

Oxides

  • Acidic Oxides: Generally non-metal oxides (e.g., CO₂, SO₂).
  • Basic Oxides: Generally metal oxides (e.g., CaO, MgO).
  • Amphoteric Oxides: Reacts with both acids and bases (e.g., Al₂O₃, ZnO).
  • Neutral Oxides: Do not react with acids or bases (e.g., CO, N₂O).

Preparation of Salts

  • Titration: Used when both reactants are soluble.
  • Neutralization: Used when starting reactant is insoluble.
  • Precipitation: Used to form insoluble salts.

Sample Reactions and Questions

  • Neutralization Example: Reaction of HCl with NaOH to form NaCl.
  • Precipitation Example: Formation of AgCl from AgNO₃ and NaCl.
  • Sample Questions: Includes predicting products and identifying pH changes.

Note: Always balance chemical equations and understand the context of the reactions (acid, base, neutral, etc.).