Lecture Notes: Acids, Bases, and Salts
Definitions
- Acid: Proton donor; donates H⁺ ions in a reaction.
- Base: Proton acceptor; reacts to form OH⁻ ions when dissolved in water.
- Alkali: A base that dissolves in water.
- Salt: Ionic substance formed from the reaction of an acid with a base.
Key Concepts
- Proton (H⁺): In the context of acids, refers to a hydrogen ion, which is a hydrogen atom that has lost its electron.
- Concentration: A concentrated solution has a small amount of water; a dilute solution has a large amount of water.
Types of Acids and Bases
- Strong Acid: Fully ionizes in solution (e.g., HCl, H₂SO₄).
- Weak Acid: Partially ionizes in solution (e.g., CH₃COOH).
- Strong Base: Fully ionizes in solution (e.g., NaOH, KOH).
- Weak Base: Partially ionizes in solution (e.g., NH₃).
pH Scale
- Ranges from 0 to 14.
- Acids: pH < 7
- Strong acid: pH 1-3
- Weak acid: pH 4-6
- Neutral: pH = 7 (e.g., water, NaCl solution)
- Bases: pH > 7
- Strong base: pH 11-14
- Weak base: pH 8-10
Identifying Acids and Bases
- Acids often start with an "H" (e.g., HCl).
- Bases often end with "OH" or contain "O" (e.g., NaOH, CaO).
Reactions
- Neutralization: Acid + Base → Salt + Water
- Acid + Metal: Acid + Metal → Salt + Hydrogen gas
- Acid + Carbonate: Acid + Carbonate → Salt + CO₂ + Water
- Base + Ammonium Salt: Base + Ammonium Salt → Ammonia gas + Water
Indicators
- Litmus:
- Universal Indicator: Provides a range of colors to indicate pH level.
- Phenolphthalein:
- Base: Pink
- Neutral/Acid: Colorless
- Methyl Orange:
- Acid: Red
- Base: Yellow
- Neutral: Orange
Oxides
- Acidic Oxides: Generally non-metal oxides (e.g., CO₂, SO₂).
- Basic Oxides: Generally metal oxides (e.g., CaO, MgO).
- Amphoteric Oxides: Reacts with both acids and bases (e.g., Al₂O₃, ZnO).
- Neutral Oxides: Do not react with acids or bases (e.g., CO, N₂O).
Preparation of Salts
- Titration: Used when both reactants are soluble.
- Neutralization: Used when starting reactant is insoluble.
- Precipitation: Used to form insoluble salts.
Sample Reactions and Questions
- Neutralization Example: Reaction of HCl with NaOH to form NaCl.
- Precipitation Example: Formation of AgCl from AgNO₃ and NaCl.
- Sample Questions: Includes predicting products and identifying pH changes.
Note: Always balance chemical equations and understand the context of the reactions (acid, base, neutral, etc.).