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Organic Chemistry Naming & Formulas

Jun 9, 2025

Overview

This lecture covers part two of IGCSE Organic Chemistry, focusing on how to name organic compounds and how to interpret their chemical and displayed formulas.

Naming Organic Compounds

  • Organic compound names tell you the homologous series and the number of carbon atoms.
  • Homologous series include alkanes, alkenes, alcohols, and carboxylic acids.
  • Names ending in "-ane" are alkanes (e.g., ethane).
  • Names ending in "-ene" are alkenes (e.g., ethene).
  • Names ending in "-ol" are alcohols (e.g., ethanol).
  • Names ending in "-oic acid" are carboxylic acids (e.g., ethanoic acid).

Carbon Atom Prefixes

  • "Meth-" indicates 1 carbon atom.
  • "Eth-" indicates 2 carbon atoms.
  • "Prop-" indicates 3 carbon atoms.
  • "But-" indicates 4 carbon atoms.
  • "Pent-" indicates 5 carbon atoms.
  • "Hex-" indicates 6 carbon atoms.

Recognizing Compounds from Formulas

  • Alkanes: contain only single carbon-carbon bonds and no functional group.
  • Alkenes: have a carbon-carbon double bond as a functional group.
  • Alcohols: have an -OH (hydroxyl) group.
  • Carboxylic acids: have a -COOH (carboxyl) group.

Examples of Naming and Drawing Formulas

  • CH₄: One carbon, all single bonds, so "methane" (alkane).
  • C₂H₄: Two carbons, double bond, so "ethene" (alkene).
  • C₃H₇O: Three carbons, contains -OH, so "propanol" (alcohol).
  • C₄H₇CO: Four carbons, contains -COOH, so "butanoic acid" (carboxylic acid).

Writing Displayed Formulas

  • Methane (CH₄): one carbon, four hydrogens, only single bonds.
  • Ethane (C₂H₆): two carbons, single bond between them, six hydrogens.
  • Ethene (C₂H₄): two carbons, double bond, four hydrogens.
  • Ethanol (C₂H₅OH): two carbons, five hydrogens, one -OH group.
  • Ethanoic acid (CH₃COOH): two carbons, three hydrogens attached to one carbon, one -COOH group.

Key Terms & Definitions

  • Homologous Series — A family of organic compounds with the same functional group and similar chemical properties.
  • Functional Group — A specific group of atoms responsible for the characteristic reactions of a compound.
  • Displayed Formula — A diagram showing all atoms and bonds in a molecule.

Action Items / Next Steps

  • Practice naming and drawing displayed formulas for given organic compounds.
  • Review the formulas for alkanes (CnH2n+2), alkenes (CnH2n), and alcohols (CnH2n+1OH).
  • Prepare for next topic in organic chemistry.