Understanding Oxides, Hydroxides, and Acids

Aug 18, 2024

Lecture Notes on Inorganic Compounds: Oxides, Hydroxides, and Acids

Introduction

  • Presenter: Andre from Med School EU
  • Topic: Inorganic Compounds based on IMAT specifications
  • Focus: Properties of Oxides, Hydroxides, and Acids

Oxides

  • Defined as chemical compounds with one or more oxygen atoms.
  • Typically binary compounds (two different elements: metal/non-metal + oxygen).
  • Examples:
    • Lithium Oxide (Li₂O)
    • Carbon Dioxide (CO₂)
    • Sulfur Dioxide (SO₂)
    • Calcium Oxide (CaO)
    • Water (H₂O)

Properties of Oxides

  1. Acidic Oxides (Acid Anhydrides):

    • Non-metal oxide + water → Acid
    • Example: SO₂ + H₂O → H₂SO₃ (Sulfurous Acid)
    • Reaction with base (e.g., NaOH) forms salt and water.
  2. Basic Oxides (Base Anhydrides):

    • Metal oxide + water → Base
    • Example: MgO + H₂O → Mg(OH)₂
    • Typically from alkali and alkaline earth metals.
    • Reaction with acid forms salt and water.
  3. Amphoteric Oxides:

    • Can react as an acid or a base.
    • Understanding requires knowing acid-base definitions.

Acid and Base Definitions

  1. Arrhenius Definition:

    • Acid: Produces H₃O⁺ in aqueous solution.
    • Base: Produces OH⁻ in aqueous solution.
  2. Brønsted-Lowry Definition:

    • Acid: Proton donor.
    • Base: Proton acceptor.

Amphoteric Oxides

  • Can function both as an acid and a base.
  • Example reactions:
    • HCl + H₂O → H₃O⁺ + Cl⁻ (H₂O acts as base)
    • NH₃ + H₂O → NH₄⁺ + OH⁻ (H₂O acts as acid)

Hydroxides

  • Hydroxide (OH⁻) ions form strong bases, especially with alkali metals.
  • Strong Bases Examples:
    • NaOH, LiOH, KOH
  • Properties:
    • Taste bitter.
    • Feel slippery (e.g., detergent).
    • Neutralize acids.

Properties of Acids

  • Form hydronium (H₃O⁺) and proton ions.
  • Taste sour.
  • Dissolve metals, releasing H₂ gas.
  • Neutralize bases.

pH Concept

  • Measures concentration of H⁺ ions in solution.
  • Scale:
    • Closer to 0 → Stronger acid
    • Closer to 14 → Stronger base
    • pH 7 → Neutral
  • Example of Neutral Compound: Purified water at pH 7.

Conclusion

  • Covered properties and examples of oxides, hydroxides, and acids.
  • Importance of understanding acid-base reactions and pH as it relates to compound behavior.