Basic Concepts of Chemistry
1. Matter
- Types of Matter:
- Pure Substances: Contain the same type of particles.
- Examples:
- Iron sheet (contains one type of particle)
- Sodium chloride (NaCl)
- Impure Substances (Mixtures): Contain different types of particles.
- Examples:
- Salt solution (contains salt and water)
- Salad (contains various ingredients)
- Key Exam Question: Why are elements and compounds called pure substances?
- Answer: They are made up of one type of particle.
- Mixtures: Impure substances made up of different types of particles.
- Important examples include: air, sea water, solutions, suspensions, colloids, and alloys like steel.
2. Properties of Metals
- Physical Properties: Can be observed without changing the identity of the substance.
- Mnemonic: "Moving Vent Should Come Late"
- M = Mass
- V = Volume
- S = Shape
- C = Color
- L = Length
- Chemical Properties: Observed when a substance undergoes a change in state.
- Mnemonic: "Moving Vent Should Come Late" (for chemical reactions)
- A = Acid
- S = Air
- B = Base
- W = Water
- C = Chemical reactions
3. Physical Quantities
- Definition: Anything that can be measured.
- Types:
- Base Physical Quantities:
- Length, Time, Mass, Temperature, Amount of Substance, Light Intensity, Electric Current.
- Derived Physical Quantities: Derived from base quantities (e.g., Speed = Length/Time).
- International System of Units (SI Units): Established in 1960 for base quantities.
- Mnemonic: "Lisa Mem Turns to a Left Age"
- L = Length (m)
- M = Mass (kg)
- T = Time (s)
- T = Temperature (K)
- S = Amount of Substance (mol)
- L = Light Intensity (cd)
- E = Electric Current (A)
- Difference between Mass and Weight:
- Mass: Amount of matter in an object (SI unit: kg)
- Weight: Force of gravity acting on an object (SI unit: N).
4. Prefixes
- Definition: Mnemonics added to units to show multiples or fractions.
- Example: 2 kg (kilo is the prefix).
- Important Prefixes:
- Positive:
- D = Deca
- H = Hecto
- K = Kilo
- M = Mega
- G = Giga
- T = Tera
- Negative:
- D = Deci
- C = Centi
- M = Milli
- U = Micro
- N = Nano
- P = Pico
5. Scientific Notations
- Definition: A method for writing very large or very small numbers.
- Example: Mass of the earth = 6 x 10^24 kg
- Diameter of nucleus = 1.7 x 10^-15 m
6. Significant Figures
- Definition: Certain and important digits in a measurement.
- Identifying Significant Figures:
- Non-decimal numbers: Count from the first non-zero digit to the last non-zero digit.
- Decimal numbers: Count from the first non-zero digit to the last digit.
7. Accuracy and Precision
- Accuracy: How close the measurement is to the actual value.
- Precision: How close multiple measurements are to each other.
- Examples:
- Accurate but not precise = One measurement matches actual value, others don’t.
- Precise but not accurate = All measurements are close to each other but not to the actual value.
8. Dimensional Analysis
- Definition: The process of converting one set of units to another.
- Example: 3045 m to km (3045 m / 1000 = 3.045 km).
- Example: 35 °C to K (35 + 273 = 308 K).
9. Laws of Chemical Combination
- Laws:
- Law of Conservation of Mass: Mass cannot be created or destroyed in a chemical reaction.
- Law of Definite Proportions: Elements combine in fixed ratios by mass.
- Law of Multiple Proportions: When two elements form different compounds, the mass ratio of the elements is a whole number.
- Gay-Lussac's Law: Pressure is directly proportional to temperature at constant volume.
- Avogadro's Law: Equal volumes of gases at the same temperature and pressure contain equal numbers of molecules.
10. Mole and Avogadro's Number
- Definition of Mole: A counting unit similar to a dozen.
- Avogadro's Number: 6.022 x 10^23 particles (atoms, molecules).
- Molar Mass: Mass of one mole of a substance (e.g., 12 g of carbon = 1 mole).
11. Molarity and Molality
- Molarity (M): Moles of solute per liter of solution.
- Formula: M = moles of solute / volume of solution (L).
- Molality (m): Moles of solute per kg of solvent.
- Formula: m = moles of solute / mass of solvent (kg).
These notes summarize the essential concepts from the first chapter of chemistry. Remember to review them for a solid understanding.