Fundamental Concepts of Chemistry

Sep 10, 2024

Basic Concepts of Chemistry

1. Matter

  • Types of Matter:
    • Pure Substances: Contain the same type of particles.
      • Examples:
        • Iron sheet (contains one type of particle)
        • Sodium chloride (NaCl)
    • Impure Substances (Mixtures): Contain different types of particles.
      • Examples:
        • Salt solution (contains salt and water)
        • Salad (contains various ingredients)
  • Key Exam Question: Why are elements and compounds called pure substances?
    • Answer: They are made up of one type of particle.
  • Mixtures: Impure substances made up of different types of particles.
    • Important examples include: air, sea water, solutions, suspensions, colloids, and alloys like steel.

2. Properties of Metals

  • Physical Properties: Can be observed without changing the identity of the substance.
    • Mnemonic: "Moving Vent Should Come Late"
      • M = Mass
      • V = Volume
      • S = Shape
      • C = Color
      • L = Length
  • Chemical Properties: Observed when a substance undergoes a change in state.
    • Mnemonic: "Moving Vent Should Come Late" (for chemical reactions)
      • A = Acid
      • S = Air
      • B = Base
      • W = Water
      • C = Chemical reactions

3. Physical Quantities

  • Definition: Anything that can be measured.
  • Types:
    • Base Physical Quantities:
      • Length, Time, Mass, Temperature, Amount of Substance, Light Intensity, Electric Current.
    • Derived Physical Quantities: Derived from base quantities (e.g., Speed = Length/Time).
  • International System of Units (SI Units): Established in 1960 for base quantities.
    • Mnemonic: "Lisa Mem Turns to a Left Age"
      • L = Length (m)
      • M = Mass (kg)
      • T = Time (s)
      • T = Temperature (K)
      • S = Amount of Substance (mol)
      • L = Light Intensity (cd)
      • E = Electric Current (A)
  • Difference between Mass and Weight:
    • Mass: Amount of matter in an object (SI unit: kg)
    • Weight: Force of gravity acting on an object (SI unit: N).

4. Prefixes

  • Definition: Mnemonics added to units to show multiples or fractions.
    • Example: 2 kg (kilo is the prefix).
  • Important Prefixes:
    • Positive:
      • D = Deca
      • H = Hecto
      • K = Kilo
      • M = Mega
      • G = Giga
      • T = Tera
    • Negative:
      • D = Deci
      • C = Centi
      • M = Milli
      • U = Micro
      • N = Nano
      • P = Pico

5. Scientific Notations

  • Definition: A method for writing very large or very small numbers.
    • Example: Mass of the earth = 6 x 10^24 kg
    • Diameter of nucleus = 1.7 x 10^-15 m

6. Significant Figures

  • Definition: Certain and important digits in a measurement.
  • Identifying Significant Figures:
    • Non-decimal numbers: Count from the first non-zero digit to the last non-zero digit.
    • Decimal numbers: Count from the first non-zero digit to the last digit.

7. Accuracy and Precision

  • Accuracy: How close the measurement is to the actual value.
  • Precision: How close multiple measurements are to each other.
  • Examples:
    • Accurate but not precise = One measurement matches actual value, others don’t.
    • Precise but not accurate = All measurements are close to each other but not to the actual value.

8. Dimensional Analysis

  • Definition: The process of converting one set of units to another.
    • Example: 3045 m to km (3045 m / 1000 = 3.045 km).
    • Example: 35 °C to K (35 + 273 = 308 K).

9. Laws of Chemical Combination

  • Laws:
    1. Law of Conservation of Mass: Mass cannot be created or destroyed in a chemical reaction.
    2. Law of Definite Proportions: Elements combine in fixed ratios by mass.
    3. Law of Multiple Proportions: When two elements form different compounds, the mass ratio of the elements is a whole number.
    4. Gay-Lussac's Law: Pressure is directly proportional to temperature at constant volume.
    5. Avogadro's Law: Equal volumes of gases at the same temperature and pressure contain equal numbers of molecules.

10. Mole and Avogadro's Number

  • Definition of Mole: A counting unit similar to a dozen.
  • Avogadro's Number: 6.022 x 10^23 particles (atoms, molecules).
  • Molar Mass: Mass of one mole of a substance (e.g., 12 g of carbon = 1 mole).

11. Molarity and Molality

  • Molarity (M): Moles of solute per liter of solution.
    • Formula: M = moles of solute / volume of solution (L).
  • Molality (m): Moles of solute per kg of solvent.
    • Formula: m = moles of solute / mass of solvent (kg).

These notes summarize the essential concepts from the first chapter of chemistry. Remember to review them for a solid understanding.