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Atomic Structure and Periodic Table

Sep 9, 2025

Overview

This lecture explains atomic structure, the organization and interpretation of the periodic table, isotopes, and how to calculate relative atomic mass using isotope abundances.

Atomic Structure

  • Atoms consist of a central nucleus (protons and neutrons) surrounded by electrons in orbit.
  • The number of protons in the nucleus determines the element.
  • Hydrogen has one proton and one electron; helium has two protons, two neutrons, and two electrons.

The Periodic Table and Nuclear Symbols

  • The periodic table organizes about 100 elements, each in a box called a nuclear symbol.
  • The atomic number (bottom left in the box) shows the number of protons and identifies the element.
  • Each element has a unique one- or two-letter symbol (e.g., C for carbon, Li for lithium, Na for sodium, Fe for iron).

Identifying Elements

  • An atom's element is defined solely by its number of protons (atomic number).
  • To identify an element, match the number of protons to its atomic number on the periodic table.

Isotopes

  • Isotopes are forms of the same element with identical numbers of protons but different numbers of neutrons.
  • Chemical behavior is nearly identical for all isotopes of an element.
  • Example: Carbon-12 has 6 protons and 6 neutrons; carbon-13 has 6 protons and 7 neutrons.

Relative Atomic Mass

  • Relative atomic mass is the weighted average mass of all isotopes of an element.
  • To calculate: Multiply each isotope's abundance by its mass, sum the results, then divide by total abundance.
  • Example for copper: Relative atomic mass = [(69.2 × 63) + (30.8 × 65)] / (69.2 + 30.8) = 63.6 (rounded to 1 decimal place).
  • The symbol for relative atomic mass is A_r.

Key Terms & Definitions

  • Atom — Smallest unit of an element, with protons, neutrons, and electrons.
  • Nucleus — Central part of an atom, containing protons and neutrons.
  • Proton — Positively charged particle in the nucleus; defines the element.
  • Neutron — Neutral particle in the nucleus.
  • Electron — Negatively charged particle orbiting the nucleus.
  • Atomic Number — Number of protons in an atom; unique to each element.
  • Isotope — Atoms of the same element with different numbers of neutrons.
  • Relative Atomic Mass (A_r) — Weighted average mass of all isotopes of an element.

Action Items / Next Steps

  • Review periodic table symbols and atomic numbers.
  • Practice calculating relative atomic mass from isotope data.
  • Learn definitions for key atomic structure terms.