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Guide to Naming Ionic and Covalent Compounds

Mar 8, 2025

Naming Ionic and Covalent Compounds

Introduction

  • Understanding naming of ionic and covalent (molecular) compounds is crucial.
  • Importance: Required throughout chemistry studies.
  • Strategy: Identify compound type first - ionic or molecular.

Compound Identification

  • Ionic Compounds
    • Consist of one metal and one nonmetal.
  • Molecular (Covalent) Compounds
    • Consist of two nonmetals.

Ionic Compounds

Without a Transition Metal

  • Naming: Metal name + Nonmetal name ending in "ide."
  • Example: Aluminum Oxide (Aluminum + Oxygen)
  • Balance charges using periodic table.
    • Aluminum 3+, Oxygen 2-
    • Balance: Aluminum subscript 2, Oxygen subscript 3 (Al2O3)

With a Transition Metal

  • Naming: Transition Metal name + Roman numeral for charge + Nonmetal name ending in "ide."
  • Example: Iron (III) Oxide
    • Iron charge determined by Roman numeral.
    • Balance: Iron subscript 2, Oxygen subscript 3 (Fe2O3)

With a Polyatomic Atom

  • Naming: Metal name + Polyatomic atom name.
  • Example: Calcium Phosphate
    • Calcium 2+, Phosphate 3-
    • Balance using parentheses: Calcium subscript 3, (PO4) subscript 2

With Transition Metals and Polyatomic Atoms

  • Naming: Transition Metal + Roman numeral + Polyatomic atom.
  • Example: Copper (II) Nitrate
    • Copper charge from Roman numeral, Nitrate -1
    • Balance: Copper does not need subscript, NO3 subscript 2

Ionic Naming from Formula

  • Formula to Name:
    • Identify elements and charges.
    • Use Roman numeral for transition metals.
  • Example 1: FeBr2 -> Iron (II) Bromide
  • Example 2: Cu3(PO4)2 -> Copper (II) Phosphate

Covalent (Molecular) Compounds

  • Two nonmetals.
  • Use prefixes (1-10) for naming, do not balance charges.

Prefixes

  • Mono, Di, Tri, Tetra, Penta, Hexa, Hepta, Octa, Nona, Deca.

Naming

  • Prefix + Nonmetal + Prefix + Nonmetal ending in "ide."
  • Example 1: Diphosphorus Pentoxide
    • "Di" = 2 phosphorus, "Pent" = 5 oxygen
  • Example 2: N3O6 -> Trinitrogen Hexaoxide
    • "Tri" = 3 nitrogen, "Hexa" = 6 oxygen

Practice

  • Importance of practicing naming.
  • Encouragement: Keep practicing, seek tutoring if needed.
  • Believe in your ability to learn anything.