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Guide to Naming Ionic and Covalent Compounds
Mar 8, 2025
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Naming Ionic and Covalent Compounds
Introduction
Understanding naming of ionic and covalent (molecular) compounds is crucial.
Importance: Required throughout chemistry studies.
Strategy: Identify compound type first - ionic or molecular.
Compound Identification
Ionic Compounds
Consist of one metal and one nonmetal.
Molecular (Covalent) Compounds
Consist of two nonmetals.
Ionic Compounds
Without a Transition Metal
Naming: Metal name + Nonmetal name ending in "ide."
Example: Aluminum Oxide (Aluminum + Oxygen)
Balance charges using periodic table.
Aluminum 3+, Oxygen 2-
Balance: Aluminum subscript 2, Oxygen subscript 3 (Al2O3)
With a Transition Metal
Naming: Transition Metal name + Roman numeral for charge + Nonmetal name ending in "ide."
Example: Iron (III) Oxide
Iron charge determined by Roman numeral.
Balance: Iron subscript 2, Oxygen subscript 3 (Fe2O3)
With a Polyatomic Atom
Naming: Metal name + Polyatomic atom name.
Example: Calcium Phosphate
Calcium 2+, Phosphate 3-
Balance using parentheses: Calcium subscript 3, (PO4) subscript 2
With Transition Metals and Polyatomic Atoms
Naming: Transition Metal + Roman numeral + Polyatomic atom.
Example: Copper (II) Nitrate
Copper charge from Roman numeral, Nitrate -1
Balance: Copper does not need subscript, NO3 subscript 2
Ionic Naming from Formula
Formula to Name:
Identify elements and charges.
Use Roman numeral for transition metals.
Example 1: FeBr2 -> Iron (II) Bromide
Example 2: Cu3(PO4)2 -> Copper (II) Phosphate
Covalent (Molecular) Compounds
Two nonmetals.
Use prefixes (1-10) for naming, do not balance charges.
Prefixes
Mono, Di, Tri, Tetra, Penta, Hexa, Hepta, Octa, Nona, Deca.
Naming
Prefix + Nonmetal + Prefix + Nonmetal ending in "ide."
Example 1: Diphosphorus Pentoxide
"Di" = 2 phosphorus, "Pent" = 5 oxygen
Example 2: N3O6 -> Trinitrogen Hexaoxide
"Tri" = 3 nitrogen, "Hexa" = 6 oxygen
Practice
Importance of practicing naming.
Encouragement: Keep practicing, seek tutoring if needed.
Believe in your ability to learn anything.
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