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Understanding Doppler and Line Broadening
Sep 22, 2024
MOOC on Lasers - Lecture Notes
Recap of Previous Lecture
Line Broadening Mechanisms
:
Homogeneous Broadening
: Response of atoms centered around a resonance frequency.
Inhomogeneous Broadening
: Different atomic groups centered around different frequencies.
Lifetime Broadening
: Discussed in the last lecture, derived expression is Lorentzian.
Expression for Lifetime Broadening
:
Line shape function:
[ g(\nu) = \frac{4\tau_L}{1 + (4\pi\tau_L(\nu - \nu_0))^2} ]
Full Width at Half Maximum (FWHM):
[ \Delta\nu = \frac{1}{2\pi\tau_L} ]
Doppler Broadening
Introduction
: Further discussion on line broadening mechanisms, focusing on Doppler broadening.
Doppler Effect
:
Apparent frequency seen by moving atoms:
[ \nu' = \nu(1 - \frac{V_z}{c}) ]
Velocity components affect frequency perception:
Atoms moving towards radiation experience higher frequencies.
Atoms moving perpendicular experience no frequency change.
Velocity Distribution
Maxwellian Distribution
: Probability of atomic velocities given by:
[ \rho(v) \propto e^{-\frac{mv^2}{2k_BT}} ]
Distribution centered around zero velocity.
Interaction with Radiation
: Atoms interact with a range of frequencies, both less than and greater than (\nu_0).
Mathematical Treatment of Doppler Broadening
Line Shape Function
:
[ g(\nu) = \int g(\nu, V_z) dV_z ]
Gaussian distribution derived for Doppler broadening.
Normalization condition:
[ \int g(\nu) d\nu = 1 ]
Peak Value of Line Shape Function
:
At (\nu = \nu_0),
[ g(\nu_0) = \sqrt{\frac{b}{\pi}} ]
Full Width at Half Maximum:
[ \Delta\nu = 2 \sqrt{\frac{\ln 2}{b}} ]
Conclusion
:
Inverse relationship between line width and peak value of the line shape function.
Comparison of Gaussian and Lorentzian Distributions
Graphical Representation
:
Gaussian: Rapidly decreases to 0.
Lorentzian: Higher value at peak, decreases more slowly.
Gain Coefficient and Population Inversion
Importance of Line Shape Function
: Determines the gain coefficient (\gamma(\nu)).
(\gamma(\nu)) is proportional to the line shape function.
Next Topic
: Achieving population inversion as a necessary condition for amplification by stimulated emission.
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