Understanding Doppler and Line Broadening

Sep 22, 2024

MOOC on Lasers - Lecture Notes

Recap of Previous Lecture

  • Line Broadening Mechanisms:
    • Homogeneous Broadening: Response of atoms centered around a resonance frequency.
    • Inhomogeneous Broadening: Different atomic groups centered around different frequencies.
  • Lifetime Broadening: Discussed in the last lecture, derived expression is Lorentzian.
  • Expression for Lifetime Broadening:
    • Line shape function:
      [ g(\nu) = \frac{4\tau_L}{1 + (4\pi\tau_L(\nu - \nu_0))^2} ]
    • Full Width at Half Maximum (FWHM):
      [ \Delta\nu = \frac{1}{2\pi\tau_L} ]

Doppler Broadening

  • Introduction: Further discussion on line broadening mechanisms, focusing on Doppler broadening.
  • Doppler Effect:
    • Apparent frequency seen by moving atoms:
      [ \nu' = \nu(1 - \frac{V_z}{c}) ]
    • Velocity components affect frequency perception:
      • Atoms moving towards radiation experience higher frequencies.
      • Atoms moving perpendicular experience no frequency change.

Velocity Distribution

  • Maxwellian Distribution: Probability of atomic velocities given by:
    [ \rho(v) \propto e^{-\frac{mv^2}{2k_BT}} ]
    • Distribution centered around zero velocity.
  • Interaction with Radiation: Atoms interact with a range of frequencies, both less than and greater than (\nu_0).

Mathematical Treatment of Doppler Broadening

  • Line Shape Function:
    [ g(\nu) = \int g(\nu, V_z) dV_z ]
    • Gaussian distribution derived for Doppler broadening.
    • Normalization condition:
      [ \int g(\nu) d\nu = 1 ]
  • Peak Value of Line Shape Function:
    • At (\nu = \nu_0),
      [ g(\nu_0) = \sqrt{\frac{b}{\pi}} ]
    • Full Width at Half Maximum:
      [ \Delta\nu = 2 \sqrt{\frac{\ln 2}{b}} ]
  • Conclusion:
    • Inverse relationship between line width and peak value of the line shape function.

Comparison of Gaussian and Lorentzian Distributions

  • Graphical Representation:
    • Gaussian: Rapidly decreases to 0.
    • Lorentzian: Higher value at peak, decreases more slowly.

Gain Coefficient and Population Inversion

  • Importance of Line Shape Function: Determines the gain coefficient (\gamma(\nu)).
    • (\gamma(\nu)) is proportional to the line shape function.
  • Next Topic: Achieving population inversion as a necessary condition for amplification by stimulated emission.