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Naming Ionic and Covalent Compounds

Jun 5, 2025

Naming Molecules

Ionic Compounds

  • Ionic Compounds: No need to specify the number of ions in the name.
    • Example: Calcium Chloride implies 1 calcium and 2 chlorides (CaCl₂).
  • The ratio is determined by common ionic charges to achieve neutrality.

Covalent Compounds

  • Covalent Compounds: Require specific naming to indicate the number of atoms.
    • Multiple combinations between two elements can exist.
    • Example: Carbon and Oxygen can form CO and CO₂, both with different properties.

Binary Molecular Compounds

  • Binary Molecular Compounds: Formed by non-metals.
  • Naming conventions:
    • Name the more metallic element (or the element further left on the periodic table) first.
    • Name the less metallic element second with the suffix '-ide'.
    • Use prefixes to indicate the number of atoms:
      • No prefix for one atom of the first element.
      • Mono (1) for the second element if it has one atom.
      • Di (2) for two atoms.
      • Example: CO is Carbon Monoxide and CO₂ is Carbon Dioxide.

Prefixes for Molecular Naming

  • Prefixes:
    • Mono- (1)
    • Di- (2)
    • Tri- (3)
    • Tetra- (4)
    • Penta- (5)
    • Hexa- (6)
    • Hepta- (7)
    • Octa- (8)
    • Nona- (9)
    • Deca- (10)
  • Special note: If the element name starts with a vowel, the final vowel in a prefix might be dropped (e.g., Dinitrogen Tetroxide instead of Dinitrogen Tetraoxide).

Examples of Naming Compounds

  • Sulfur Hexafluoride: SF₆
  • Dinitrogen Tetroxide: N₂O₄
  • Iodine Heptafluoride: IF₇

Examples of Molecular Formulas from Names

  • Phosphorus Pentachloride: PCl₅
  • Carbon Tetrachloride: CCl₄
  • Dinitrogen Trioxide: N₂O₃

Summary

  • Understand the fundamental rules for naming both ionic and covalent compounds.
  • Apply prefixes appropriately based on the number of atoms in the molecule.
  • Be aware of vowel-dropping when naming compounds with elements that start with vowels.